Research on Warm White LED Lighting Devices Based on Carbon Nano Dots

The Qu Songnan research group of the Changchun Institute of Optics and Mechanics of the Chinese Academy of Sciences has developed carbon nano-dots with a fluorescence quantum efficiency of up to 46% in the orange-red band, which is the highest in the world. Related results were recently published in Advanced Materials.

Luminescent carbon nano-dots are new types of nano-luminescent materials that have emerged in the past decade and have attracted widespread attention in the world. The bottleneck facing the development of this field is the lack of means to regulate the band gap of carbon nano-dots and the method of enhancing the quantum efficiency of fluorescence. At present, carbon nano-dots have achieved relatively efficient luminescence in the blue and green bands, but in the long wavelength band of the visible region, especially the orange to red band, there is a lack of high-efficiency luminescent carbon nano-dots.

Qu Songnan's research group further developed a method for regulating the luminescence band gap of carbon nano-dots. By regulating the degree of polycondensation of urea and citric acid assemblies, the solvothermal reaction of DMF as a solvent extends the absorption band of carbon nano-dots to green. In the optical band, by further metal cation passivation surface defect state treatment, the fluorescence quantum efficiency of the carbon nano-dots in the orange-red light band is as high as 46%. Researchers have combined the carbon nano-dots with starch to develop an orange-red phosphor based on carbon nano-dots, and to realize a warm white-light LED lighting device based on carbon nano-dots.

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